Hydrochemistry monitoring and risk assessment of mining & uranium tailing in transboundary river watershed of CA countries
Hydrochemistry monitoring and risk assessment of mining & uranium tailing in transboundary river watershed (Phase 1)
Tech Area / Field
- ENV-WPC/Water Pollution and Control/Environment
- OBS-NAT/Natural Resources and Earth Sciences/Other Basic Sciences
6 Project underway
Senior Project Manager
Institute of Water Problem, Hydropower and Ecology, Tajikistan, Dushanbe
- National Nuclear Center of the Republic of Kazakstan / Institute of Nuclear Physics, Kazakhstan, Almaty\nCentral-Asian Institute of Applied Geosciences, Kyrgyzstan, Bishkek\nInternational Center for Biosaline Agriculture for Central Asia and Caucasus, Tashkent sub-office, Uzbekistan, Tashkent\nInstitute of Biology and Pedology, Kyrgyzstan, Bishkek
Project summaryThe main goal of the proposed project is to conduct radio-ecological, hydro-chemical and geochemical investigation of the extent pollution in transboundary areas of Central Asian river Basin (Syr-Darya and Amu-Darya Rivers and its tributaries), where the main uranium, gas and gold mining industries are concentrated. To study the dynamics of changes in contamination by comparing the data obtained in the course of this project with the 15 year old date base of Navruz investigation.
In the year 2000 scientists from four Central Asian countries, Kazakhstan, Uzbekistan, Kyrgyzstan and Tajikistan implemented joint radio-ecological and geochemical monitoring of the Transboundary Rivers of the Central Asia under the project named “Navruz.” Implementation of the project continued for about 10 years. The project was carried out under aegis of Sandia National Laboratories (SNL) USA. The Navruz Project generated a large database of more than 100 water/land quality parameters at 60 sites throughout the basin using standardized methods among the four participating countries. Parameters included natural and technogenic radioactive nuclides (137Cs, 40K, decay series of 238U, 235U, 232Th) and toxic admixtures (U, Pb, Hg, Se, Sb, As, etc.). Research has continued within the limits of ISTC projects. A shared website at SNL contains the database. The database included isotope and geochemical data on the composition of water, suspension, bottom sediment, aquatic vegetation and surrounding soils (H.D.Passell, 2003).
To obtain an improved understanding of the environmental condition of land-water-ecosystem of transboundary Rivers basin, samples of water, aqueous suspensions, soil, bottom sediment and vegetation will be collected from the rivers, lateral inflows and other land sites to analyze concentration of isotope-chemical elements. The samples collected in the field will be processed and analyzed by the X-ray fluorescence analysis (XRF) and by gamma spectrometers in the domestic’s laboratories in Dushanbe, Almaty and Bishkek. X percent of the samples processed and distributed into chemically clean jars, will be shipped to Institute of Nuclear Physics at Almaty for the neutron activation analysis (NAA). Both methods, the XRF and NAA will complement each other to analyze the 38 elements- major: Ca, Fe, K, Mn, Na, Ti and trace-elements: As, Au, Ba, Br, Ce, Co, Cr, Cs, Cu, Eu, Ga, Hf, La, Lu, Mo, Nb, Nd, Ni, Rb, Sb, Se, Sr, Sc, Sm, Ta, Th, U, V, Y, Yb, Zn, Zr. The isotopes 137Cs, 40K, decay series of 238U, 235U, 232Th will be determined by gamma spectrometers.
The result will be compiled into a database and GIS maps will be created of radionuclide isotopes and geochemical elements within the study areas. One major objective is to identify and highlight the anomalous zones with increased health risks for local residents.
The new isotope-geochemical data will be compared with the Navruz data obtained, and will assess the degree of change in the ecological status of the Amu-Darya and Syr- Darya Rivers and its tributaries.
The results will give us an opportunity to predict changes in ecological status of rivers under different scenarios of global and regional climate change and other anthropogenic impacts.
The proposed geochemical and radionuclide study can also identify land, rivers and reservoirs contaminated by heavy metals, other inorganic toxins and isotopes. This study becomes particularly urgent; taking into account former large number of uranium Mountain-metallurgical enterprises, as well as uranium factories located in the up and middle stream of the Syr-Darya and accumulated more than 100 million tons of uranium production wastes.
The Navruz study identified a heavy contamination of the Vakhsh River and its tributaries with mercury. This pollution has an anthropogenic character and was related with the legal and illegal extraction of native gold. Mercury pollution is also observed in the main tributaries of the river. Reference? Similar contamination was found in Tajikistan during this study. In some places the concentration of mercury was more than 800x average abundance in the Earth crust or 300x MPC for soils. The high concentration of mercury was traced down to the mouth of the Vakhsh River, and appeared highest in the areas of gold mining.
Unfortunately, only 12 points on the Vakhsh River were investigated during the Navrus study. Other rivers of Tajikistan and other countries have not been investigated for mercury concentration. Gold mining in Central Asia has occurred since ancient times. Auric are all tributaries of the Amu-Darya River. The most famous river- Zarafshan is translated as "gold bearing."
Moreover, the basins of the Amu-Darya and the Syr-Darya are polluted with other toxic metals besides mercury. In the upper reaches of the rivers there is widespread contamination with toxic metals as: Hg, Sb, As, Ba, and U. In the Central Asia Countries extraction, enrichment and metallurgical is repartition of these metals is carried out. The accident at tailing pipeline of Anzob mining factory led to significant pollution of bottom sediments of the Zarafshan with tailings particles. In the composition of the waste was stibnite, cinnabar, barite and other minerals.
The staff of the proposed project have sufficient experience in implementing projects of the International Science and Technology Center (ISTC). In frame of regional experiment Navruz (Kazakhstan, Kyrgyzstan, Uzbekistan, Tajikistan and the United States) monitored for over 10 years (1999-2009) radiation and ecological condition of the Transboundary Rivers and their main feeders.
The International Science and Technology Center (ISTC) is an intergovernmental organization connecting scientists from Kazakhstan, Armenia, Tajikistan, Kyrgyzstan, and Georgia with their peers and research organizations in the EU, Japan, Republic of Korea, Norway and the United States.
ISTC facilitates international science projects and assists the global scientific and business community to source and engage with CIS and Georgian institutes that develop or possess an excellence of scientific know-how.